Beilstein J. Org. Chem.2016,12, 1410–1420, doi:10.3762/bjoc.12.135
, octafluorooctatetraene, 6-radialene, pentalene, phenalenium+, naphthalene and octafluoronaphthalene. The HOMO of a d10 ML2 group (with b2 symmetry) interacting with the LUMO of the polyene was used as a model to explain the occurrence of minima and maxima on the potential energy surface.
Keywords: d10metalcomplexes
PDF
Graphical Abstract
Figure 1:
The four coordination geometries for d10 polyene-ML2 complexes along with their hapto numbers and e...